Mixed Micelles Formed by Cationic Surfactants and Anionic Hydrophobically Modified Polyelectrolytes

Wormlike micelles formed by mixed cationic and anionic gemini surfactants in aqueous solution.

The formation and the properties of wormlike micelles in aqueous solutions of mixed cationic and anionic gemini surfactants, 2-hydroxyl-propanediyl-α,ω-bis(dimethyldodecylammonium bromide) (12-3(OH)-12) and O,O'-bis(sodium 2-dodecylcarboxylate)-p-benzenediol (C(12)ϕC(12)), have been studied by steady-state and dynamic rheological measurements at 25°C. With the addition of a small amount of C(12...

Wormlike Micelles Formed by Synergistic Self-Assembly in Mixtures of Anionic and Cationic Surfactants

Self-assembly in mixtures of cationic and anionic surfactants occurs synergistically because of attractive interactions between the oppositely charged headgroups. Here, such effects are exploited to obtain highly viscoelastic fluids at low total surfactant concentration. The systems considered are mixtures of the C18tailed anionic surfactant, sodium oleate (NaOA), and cationic surfactants from ...

Thesis book INTERACTIONS BETWEEN CATIONIC POLYELECTROLYTES AND ANIONIC SURFACTANTS

Interactions between cationic starch and mixed anionic surfactants

The interactions of cationic starch (CS, degree of substitution=0.8)/mixed anionic surfactant/water systems were investigated. The surfactants investigated were sodium dodecyl sulphate (SDS), sodium octanoate (NaOct), sodium decanoate (NaDe), sodium dodecanoate (NaDod), sodium oleate (NaOl ) and sodium erucate (NaEr). The concentration of CS varied from 0.001 to 10 wt.%. The effect of mixing on...

Mixed micelles of cationic surfactants and sodium cholate in water.

Critical micelle concentrations (CMCs) of cationic surfactant (alkyltrimethylammonium bromides, CnTABr, where n = 10, 12, 14, 16 and 18), and a bile salt sodium cholate (NaC) were determined from surface tension, conductance and dye solubilization methods, while of their equimolar mixtures from surface tension and dye solubilization methods. The interaction parameter (beta) obtained from analys...